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O-acylation of ketoximes of the furan and thiophene series in the liquid-solid body system under interphase catalysts conditions

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The acrylation of 2-furanyl- and 2-thienylalkylketoximes by acyl chlorides in a two-phase catalytic system (solid K2CO3-C6H6-18-crown-6) at room temperature leads to a selective formation of the corresponding O-acetylketoximes in the form of a mixture of E- and Z-isomers.

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Additional information

Latvian Institute of ORganic Synthesis, Riga, LV-1006. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 886–890, July, 1994. Original article submitted April 12, 1994.

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Abele, É., Popelis, Y., Gavars, M. et al. O-acylation of ketoximes of the furan and thiophene series in the liquid-solid body system under interphase catalysts conditions. Chem Heterocycl Compd 30, 762–766 (1994). https://doi.org/10.1007/BF01169629

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  • DOI: https://doi.org/10.1007/BF01169629

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