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Chemistry of Heterocyclic Compounds

, Volume 1, Issue 1, pp 27–29 | Cite as

Study of furan compounds. XXIX. Stereodirection of a reaction yielding 1, 6, 8-trioxaoispiro[4.1.4.2]tridecene-12

  • A. A. Ponomarev
  • I. A. Markushina
Article
  • 38 Downloads

Abstract

Dielectric constants of solutions of 1, 6, 8-trioxadispiro[4.1.4.2]tridecene-12 and 1, 6, 8-trioxadispiro[4.1. 4.2]tridecane are determined, and the dipole moments calculated.

Comparison of experimental and calculated dipole moments shows that electrolysis of a solution of 2, 5-furandipropanol-3 in methanol yields trans-1, 6, 8-trioxadispiro[4.1.4.2]tridecene-12, thus indicating that the reaction of electrolytic alkoxylation of α, α′-furandialkanol-3s clearly differs from the stated stereodirection.

Keywords

Methanol Organic Chemistry Dielectric Constant Dipole Moment Furan 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© The Faraday Press, Inc. 1965

Authors and Affiliations

  • A. A. Ponomarev
    • 1
  • I. A. Markushina
    • 1
  1. 1.Chernyshevskii Saratov State UniversityUSSR

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