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Chemistry of Heterocyclic Compounds

, Volume 31, Issue 5, pp 589–595 | Cite as

Synthesis and properties of derivatives of symtriazine. 17. Synthesis of 2-methyl-4,6-disubstituted and 2,4-dimethyl-6-substituted sym-triazines by reduction of the corresponding trichloromethyl derivatives

  • V. I. Kelarev
  • V. N. Koshelev
  • N. V. Belov
  • R. A. Karakhanov
  • O. V. Malova
Article

Abstract

The reduction of trichloromethyl groups in sym-triazine derivatives to methyl groups is studied. It is shown that 2-R-4, 6-bis (trichloromethyl)-sym-triazines can be reduced to 2-R-4, 6-dirnethyl-sym-triazines with zinc dust in ethanol or with lithium aluminum hydride in THF. 2-Amino, N-substituted 2-amino-, and 2-alkoxy-4-trichloromethyl-6-R-sym-triazines are reduced to the corresponding methyl derivatives by boiling with lithium aluminum hydride in dibutyl ether.

Keywords

Aluminum Methyl Ether Zinc Dust 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • V. I. Kelarev
  • V. N. Koshelev
  • N. V. Belov
  • R. A. Karakhanov
  • O. V. Malova

There are no affiliations available

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