Abstract
The dehydrogenation of a series of alkylpyrïdines has been studied on vanadium and molybdenum oxide-containing catalysts in the presence of oxygen of the air and sulfur dioxide gas. A dependence was shown of the catalytic and physicochemical properties of the catalysts indicated on their composition and method of preparation. The optimum catalyst composition and the conditions of carrying out the reaction to provide high activity and selectivity when making vinylpyridines were determined. The relative reactivity of the alkylpyridines investigated on dehydrogenation and further oxidation was determined.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. I. Farberov, B. F. Ustavshchikov, A. M. Kut'in, T. P. Vernova, and E. V. Yarosh, Chemistry, Teclmology, and Application of Pyridine Derivatives. Proceedings of the Conference on the Chemistry of Heterocyclic Compounds. Riga. Izd-vo Akad. Nauk LatvSSR (1960), p. 97.
N. F. Kazarinova, E. P. Babin, K. A. Solomko, and M. I. Kotelenets, Zh. Prikl. Khim.,36, 646 (1963).
I. P. Belomestnykh, N. V. Voikina, and T. A. Markova, Catalytic Synthesis of Vinylpyridine Compounds. Conference on Heterogeneous Catalysis in Heterocyclic Chemistry. Abstracts. Riga (1981), p. 176.
G. P. Kotel'nikov, L. V. Strunnikova, V. B. Sidnev, and A. M. Kut'in, Investigation and Development of the Technology of Manufacturing Monomers and Synthetic Rubbers [in Russian], Central Scientific-Research Institute of Petrochemical Technology (TsNIITENeftekhim.), Moscow (1981), p. 103.
G. E. Vrieland, J. Catal.,111, 1 (1988).
J. F. McMahon, British Patent 115,076 (1966).
R. N. Volkov, V. P. Panova, I. P. Belomestnykh, G. V. Shakhnovich, and G. V. Isagulyants, Neftekhim.,25, 468 (1985).
O. K. Bogdanova, I. P. Belomestnykh, N. V. Voikina, M. S. Kuznetsova, and N. I. Torsunova, Authors Certificate 237,114 USSR; Byull. Izobret. No. 8 (1969).
I. P. Belomestnykh, N. S. Kozlov, E. A. Skrigan, G. V. Isagulyants, G. V. Milorava, and G. V. Shakhnovich, Neftekhim.,25, 599 (1985).
N. S. Kozlov, G. V. Isagulyants, E. A. Skrigan, and I. P. Belomestnykh, Proceedings of the 8th International Congress on Catalysis, Vol. 4, West Berlin (1984), p. 485.
I. P. Belomestnykh, E. A. Skrigan, N. N. Rozhdestvenskaya, and G. V. Isaguliants, IIIrd European Workshop Meeting on “New Developments in Selective Oxidation,” Preprints, Vol. 1, Belgium (1991).
A. V. Simakov, N. N. Sazonova, S. A. Ven'yaminov, I. P. Belomestnikh, N. N. Rozhdestvenskaya, and G. V. Isagulyants, Kinet. Katal.,30, 684 ( (1989).
M. Che, F. Figueras, M. Forissier, J. McAteer, M. Perrin, J. L. Portefaix, and H. Praliaud, Proceedings of the 6th International Congress on Catalysis, London (1976), Preprints, A17.
I. P. Belomestnykh, N. N. Rozhdestvenskaya, and G. V. Isagulyants, Neftekhim.,32, 220 (1992).
Additional information
N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 117913. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 802–811, June, 1994. Original article submitted April 19, 1994.
Rights and permissions
About this article
Cite this article
Belomestnykh, I.P., Rozhdestvenskaya, N.N. & Isagulyants, G.V. Oxidative dehydrogenation of alkylheteroaromatic compounds 1. Catalysts containing vanadium and molybdenum for the oxidative dehydrogenation of alkylpyridines. Chem Heterocycl Compd 30, 701–708 (1994). https://doi.org/10.1007/BF01166312
Issue Date:
DOI: https://doi.org/10.1007/BF01166312