Abstract
1,3-Diazaadamantanes containing hydrogen atoms or a hydroxyl or oxime group at C(6), under the action of 2 moles of aralkyl halides, are converted in alkaline aqueous media to 3,7-diaralkyl-3, 7-diazabi cyclo(3.3.1]nonanes containing the indicated groups at C(9). Analogously, quaternary salts of 1,3-diaza-adamantanes containing hydrogen atoms or a hydroxyl group at C(6) are converted in an alkaline aqueous medium to the corresponding 3-alkyl-3,7-diazabicyclo[3.3.1]nonanes containing the indicated groups at C(9).
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Ts. E. Agadzhanyan, A. D. Arutyunyan, and G. G. Adamyan, Khim. Geterotsikl. Soedin., No. 3, 397 (1994).
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G. G. Minasyan, M. B. Mkrtchyan, and Ts. E. Agadzhanyan, Arm. Khim. Zh.,39, 44 (1986).
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For Communication 19, see [1].
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 401–406, March, 1994.
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Minasyan, G.G., Arutyunyan, A.D., Adamyan, G.G. et al. Synthesis and conversions of polyhedral compounds 20. Synthesis of certain derivatives of 3,7-diazabycyclo[3.3.1]nonane. Chem Heterocycl Compd 30, 353–357 (1994). https://doi.org/10.1007/BF01165705
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DOI: https://doi.org/10.1007/BF01165705