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5-[5-R-furfurylidene]-2,2-dimethyl-1,3-dioxane-4,6-diones 6. Synthesis, structure, and properties of substituted furylimino- and furfurylidenephosphoranes. Molecular and crystal structure of N-[5-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)methyl-2-furylimino(triphenyl)phosphorane

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Furylimino- and furfurylidenephosphoranes have been synthesized by sequential conversions of 5-unsubstituted and 5-methylfurfut),Iidetiedio.yanediones. The ylide fragment linked directly with the furfurylidenedioxanedione residue displays strong electron-donating properties, as a result of which resonance occurs in the system of conjugated bonds. The molecular and crystal structure of the iminophosphorane was studied by x-ray structural analysis and the resonance of the bonds in the molecule was confirmed.

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Authors and Affiliations

  1. Kuban State Technological University, 350072, Krasnodar

    G. D. Krapivin, N. I. Val'ter, V. E. Zavodnik, T. Ya. Kaklyugina & V. G. Kul'nevich

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  1. G. D. Krapivin
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  2. N. I. Val'ter
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  3. V. E. Zavodnik
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  4. T. Ya. Kaklyugina
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  5. V. G. Kul'nevich
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 335–344, March, 1994.

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Krapivin, G.D., Val'ter, N.I., Zavodnik, V.E. et al. 5-[5-R-furfurylidene]-2,2-dimethyl-1,3-dioxane-4,6-diones 6. Synthesis, structure, and properties of substituted furylimino- and furfurylidenephosphoranes. Molecular and crystal structure of N-[5-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)methyl-2-furylimino(triphenyl)phosphorane. Chem Heterocycl Compd 30, 296–304 (1994). https://doi.org/10.1007/BF01165694

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  • DOI: https://doi.org/10.1007/BF01165694

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