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Chemistry of Heterocyclic Compounds

, Volume 32, Issue 2, pp 197–201 | Cite as

Oxidative reactions of azines. 1. Ketohydroxylation of 4-Phenyl-1,2,5,6-tetrahydropyrines. Synthesis and structure of 3,4-dihydroxy-4-phenylpiperidin-2-ones and their acetoxy derivatives

  • A. T. Soldatenkov
  • I. A. Bekro
  • Zh. A. Mamyrbekova
  • S. A. Soldatova
  • A. Temesgen
  • N. D. Sergeeva
  • L. N. Kuleshova
  • V. N. Khrustalev
Article
  • 28 Downloads

Abstract

N-Alkyl substituted 4 phenyl-1.2,5,6-tetrahydropyridines which do not undergo Wagner hydroxylation are converted in good yields to the corresponding 3,4-dihydroxy-2-oxopiperidines under modified conditions for this reaction. The molecular structures of a 3,4-dihydroxy-4-phenylpiperidin-2-one and its diacetatate have been studied by x-ray crystalographic analysis.

Keywords

Organic Chemistry Modify Condition Molecular Structure Oxidative Reaction Good Yield 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    T. N. Maksimova, V. B. Mochalin, and B. V. Unkovskii, Khim. Geterotsikl. Soedin., No. 6, 783 (1980).Google Scholar
  2. 2.
    C. J. Schmidle and R. C. Mansfield, J. Am. Chem. Soc., 77, 5698 (1955).Google Scholar

Copyright information

© Plenum Publishing Corporation 1996

Authors and Affiliations

  • A. T. Soldatenkov
    • 1
  • I. A. Bekro
    • 1
  • Zh. A. Mamyrbekova
    • 1
  • S. A. Soldatova
    • 1
  • A. Temesgen
    • 1
  • N. D. Sergeeva
    • 1
  • L. N. Kuleshova
    • 1
  • V. N. Khrustalev
    • 1
  1. 1.Russian University of National FriendshipMoscow

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