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Orientation effects in phenoxathiin acetylation and formylation

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

In acetylation and formylation of phenoxathiin, besides 2-acyl-substituted main products, the 3-isomers form in ca. 10% yield. The structure of 3-acetylphenoxathiin isolated by fractional crystallization from the mixture resulted after acetylation was proved by means of physical and chemical methods.

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Authors
  1. O. Maior
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  2. D. Stoicescu
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  3. D. Gavriliu
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Additional information

Faculty of Chemistry, Organic Chemistry Department, University of Bucharest, 90-92 Panduri Road, Romania. SINDAN S.R.L. 11 1 Mai Blv., Bucharest, Romania.Published in Khlmiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1261–1265, September, 1996. Original article submitted May 8, 1996; revision submitted July 30, 1996.

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Maior, O., Stoicescu, D. & Gavriliu, D. Orientation effects in phenoxathiin acetylation and formylation. Chem Heterocycl Compd 32, 1084–1088 (1996). https://doi.org/10.1007/BF01164717

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  • DOI: https://doi.org/10.1007/BF01164717

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