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Free radicals in the electrochemical reduction of 1,2-dihydro-3-nitropyridine derivatives

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The formation of primary radical anions of N-substituted 1, 2-dihydro-3-nitropyridines was confirmed by the ESR method under conditions of electrochemical generation of free radicals, and their structure was established. The causes of the different ability of 1,2- and 1,4-dihydro-3-nitropyridines to form free radicals during electrochemical reduction that are stable enough to be studied by the ESR method are examined.

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Authors
  1. Ya. Stradyn'
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  2. R. Gavats
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  3. L. Baumane
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  4. B. Vigante
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  5. G. Duburs
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Additional information

Latvian Institute of Organic Synthesis, Riga LV-1006.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1222–1227, September, 1996. Original article submitted May 20, 1996.

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Stradyn', Y., Gavats, R., Baumane, L. et al. Free radicals in the electrochemical reduction of 1,2-dihydro-3-nitropyridine derivatives. Chem Heterocycl Compd 32, 1047–1051 (1996). https://doi.org/10.1007/BF01164710

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  • DOI: https://doi.org/10.1007/BF01164710

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