Advertisement

Chemistry of Heterocyclic Compounds

, Volume 32, Issue 9, pp 1023–1026 | Cite as

Fluorobenzo-1,4-thiazine oxides from bis-(vinylsulfinyl)-and bis(vinylsulfonyl)-fluorobenzenes and 2-aminoethanol

  • S. V. Amosova
  • V. I. Gostevskaya
  • G. M. Gavrilova
  • V. N. Nesterov
  • Yu. T. Struchkov
  • L. N. II'icheva
Article

Abstract

It has been established that 1, 2, 4, 5-tetrafluoro-3, 6-bis (vinylsulfinyl)- and 1, 2, 4, 5-tetrafluoro-3, 6bis(vinylsulfonyl)benzenes react with 2-aminoethanol by nucleophilic addition at the activated double bond with replacement of fluorine atoms on the benzene ring by the amino group of 2-aminoethanol to give 4, 9-bis(2 hydroxyethyl)-5,10-difluoro-1, 2, 3, 4, 6, 7, 8, 9-octahydrobenzo[1, 2-b; 5, 4-b]di-1, 4-thiazine 1,6-dioxide and 1, 1, 6, 6-tetraoxide respectively.

Keywords

Oxide Benzene Organic Chemistry Double Bond Fluorine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    G. G. Yakobson (ed.). Reactivity of Polyfluoroaromatic Compounds [in Russian], Nauka, Siberian Branch (SO), Novosibksk (1983), p. 17.Google Scholar
  2. 2.
    N. Ishikawa, Compounds of Fluorine. Synthesis and Application [Russian translation], Mir, Moscow (1990), p. 306.Google Scholar
  3. 3.
    S. V. Amosova, V. I. Gostevskaya. G. M, Gavrilova, V N. Nesterov, and Yu. T Struchkov, lzv. Akad. Nauk, Ser. Khim., No. 2.430(1996),Google Scholar
  4. 4.
    S. V. Amosova, V. I. Gostevskaya, G. M. Gavrilova, A V. Afonin, and D.-S. D. Toryashinova, Zh. Org. Khim.,29, 2416 (1993).Google Scholar
  5. 5.
    F. H. Allen, 0 Kennard, D. G. Watson, L. Brummer. A. G. Orpen, and R. Taylor, J. Chem. Soc., Perkin Trans. 2, No. 12, 1 (1987Google Scholar
  6. 6.
    Robinson and G. M. Sheldrick, Crystallographic Computing - Techniques and New Technologies, Oxford Univ. Press, Oxford (1988). p. 366.Google Scholar

Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • S. V. Amosova
  • V. I. Gostevskaya
  • G. M. Gavrilova
  • V. N. Nesterov
  • Yu. T. Struchkov
  • L. N. II'icheva

There are no affiliations available

Personalised recommendations