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Fluorobenzo-1,4-thiazine oxides from bis-(vinylsulfinyl)-and bis(vinylsulfonyl)-fluorobenzenes and 2-aminoethanol

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

It has been established that 1, 2, 4, 5-tetrafluoro-3, 6-bis (vinylsulfinyl)- and 1, 2, 4, 5-tetrafluoro-3, 6bis(vinylsulfonyl)benzenes react with 2-aminoethanol by nucleophilic addition at the activated double bond with replacement of fluorine atoms on the benzene ring by the amino group of 2-aminoethanol to give 4, 9-bis(2 hydroxyethyl)-5,10-difluoro-1, 2, 3, 4, 6, 7, 8, 9-octahydrobenzo[1, 2-b; 5, 4-b]di-1, 4-thiazine 1,6-dioxide and 1, 1, 6, 6-tetraoxide respectively.

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References

  1. G. G. Yakobson (ed.). Reactivity of Polyfluoroaromatic Compounds [in Russian], Nauka, Siberian Branch (SO), Novosibksk (1983), p. 17.

  2. N. Ishikawa, Compounds of Fluorine. Synthesis and Application [Russian translation], Mir, Moscow (1990), p. 306.

    Google Scholar 

  3. S. V. Amosova, V. I. Gostevskaya. G. M, Gavrilova, V N. Nesterov, and Yu. T Struchkov, lzv. Akad. Nauk, Ser. Khim., No. 2.430(1996),

  4. S. V. Amosova, V. I. Gostevskaya, G. M. Gavrilova, A V. Afonin, and D.-S. D. Toryashinova, Zh. Org. Khim.,29, 2416 (1993).

    Google Scholar 

  5. F. H. Allen, 0 Kennard, D. G. Watson, L. Brummer. A. G. Orpen, and R. Taylor, J. Chem. Soc., Perkin Trans. 2, No. 12, 1 (1987

  6. Robinson and G. M. Sheldrick, Crystallographic Computing - Techniques and New Technologies, Oxford Univ. Press, Oxford (1988). p. 366.

    Google Scholar 

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Authors
  1. S. V. Amosova
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  2. V. I. Gostevskaya
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  3. G. M. Gavrilova
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  4. V. N. Nesterov
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  5. Yu. T. Struchkov
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  6. L. N. II'icheva
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Additional information

Irkutsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences (SO RAN), Irkutsk 664033. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1195–1198, September, 1996. Original article submitted June 5, 1996.

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Amosova, S.V., Gostevskaya, V.I., Gavrilova, G.M. et al. Fluorobenzo-1,4-thiazine oxides from bis-(vinylsulfinyl)-and bis(vinylsulfonyl)-fluorobenzenes and 2-aminoethanol. Chem Heterocycl Compd 32, 1023–1026 (1996). https://doi.org/10.1007/BF01164706

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  • DOI: https://doi.org/10.1007/BF01164706

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