Skip to main content
Log in

Reduction of selenious acid by hydrazine sulphate. Volumetric determination of selenium

  • Originalabhandlungen
  • Published:
Fresenius' Zeitschrift für analytische Chemie Aims and scope Submit manuscript

Summary

A volumetric method of estimating selenium, depending upon the reduction of selenious acid by excess hydrazine sulphate solution and titration of the excess against KIO3 to the iodine monochloride end point, has been described. Determination of tellurium on these lines is suggested.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Jamieson, G. S.: Amer. J. Sci.33, 352 (1912); cf. Z. analyt. Chem.52, 782 (1913).

    Google Scholar 

  2. Jannasch, P., andM. Müller: Ber. dtsch. chem. Ges.31, 2393 (1898); cf. Z. analyt. Chem.50, 507, 515 (1911);53, 430 (1914).

    Google Scholar 

  3. Jannek, J., andJ. Meyer: Ber. dtsch. chem. Ges.46, 2876 (1913); cf. Z. analyt. Chem.53, 407 (1914).

    Google Scholar 

  4. Kolthoff, I. M.: J. Amer. chem. Soc.46, 2009 (1924); cf. Z. analyt. Chem.66, 469 (1925).

    Google Scholar 

  5. Kurtenacker, A., andH. Kubina: Z. analyt. Chem.64, 388 (1924).

    Google Scholar 

  6. Lang, R.: Z. anorg. allg. Chem.142, 280 (1925); cf. Z. analyt. Chem.67, 42 (1925/26).

    Google Scholar 

  7. Lang, R.: Newer Methods of Volumetric Chemical Analysis, p. 89. Edited by W. Böttger, Chapman and Hall, Ltd., London 1938.

    Google Scholar 

  8. Pellini, G.: Gazz. chim. ital.33, 515. (1903): cf. Z. analyt. Chem.50, 521 (1911).

    Google Scholar 

  9. Pellini, G., andE. Spellta: Gazz. chim. ital.33, 89 (1903); cf. Z. analyt. Chem.50, 509 (1911).

    Google Scholar 

  10. Penneman, R. A., andL. F. Audrieth: Analyt. Chemistry20, 1058 (1948).

    Google Scholar 

  11. Strecker, W., andL. Schartow: Z. analyt. Chem.64, 218 (1924).

    Google Scholar 

  12. Vogel, A. I.: A Text Book of Quantitative Inorganic Analysis, p. 362. London: Longmans, Green and Co. 1948.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

The author is indebted to Professor S. S.Joshi for facilities and kind interest in the work. The award of a Scientific Man Power Committee Research Fellowship is also gratefully acknowledged.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Suseela, B. Reduction of selenious acid by hydrazine sulphate. Volumetric determination of selenium. Z. Anal. Chem. 147, 13–15 (1955). https://doi.org/10.1007/BF01134869

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01134869

Keywords

Navigation