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Atranes. IV. 1-Alkoxysilatranes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A new method of synthesizing 1-alkoxysilatranes

is described. It is based on transesterification of lower tetraalkoxysilanes with an equimolar mixture of triethanolamine and appropriate alcohol. The method is used to prepare 15 compounds of this type in 50–90% yields. Of these only one, R = = C2H5, was previously known. Their solubilities in various solvents are found. Molecular weight determinations show them to be monomeric.

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References

  1. M. G. Voronkov and G. I. Zelchan, KhGS, 51, 1965.

  2. M. G. Voronkov, I. B. Mazheika, and G. I. Zelchan, KhGS, 58, 1965.

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  4. M. G. Voronkov and G. I. Zelchan, Author's Certificate 162139, 1964.

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Authors and Affiliations

  1. Institute of Organic Synthesis AS Latvian SSR, Riga

    M. G. Voronkov & G. I. Zelchan

Authors
  1. M. G. Voronkov
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  2. G. I. Zelchan
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Additional information

For Part III see [3].

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Voronkov, M.G., Zelchan, G.I. Atranes. IV. 1-Alkoxysilatranes. Chem Heterocycl Compd 1, 137–140 (1965). https://doi.org/10.1007/BF01046669

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  • DOI: https://doi.org/10.1007/BF01046669

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