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Chemistry of Heterocyclic Compounds

, Volume 1, Issue 2, pp 128–129 | Cite as

Investigation of furan compounds XXX. Intramolecular alkoxylation of furfuryl-substituted mono- and bicyclic alcohols

  • A. A. Ponomarev
  • I. A. Markushina
Article
  • 38 Downloads

Abstract

On electrolysis mono- and bicyclic furfuryl-substituted alcohols undergo intramolecular alkoxylation, giving polycyclic spirans. Spiro[perhydrobenzofuran-2, 2-(5′-methoxy, 5′H)furan] and spiro[4H, 5H, 6H, 11H-naphtho-(α,β)-furan-2(3H)] [2′-(5′-methoxy, 5′H)furan], hitherto not described, are prepared in this way. On catalytic hydrogenation they give the previously unknown spiro[perhydrobenzofuran-2, 2′-tetrahydrofuran] and spiro[4H, 5H, 6H, 11H-naphtho-(α,β)-furan-2(3H)][2′-tetrahydrofuran].

Keywords

Hydrogenation Alcohol Organic Chemistry Methoxy Furan 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© The Faraday Press, Inc. 1966

Authors and Affiliations

  • A. A. Ponomarev
    • 1
  • I. A. Markushina
    • 1
  1. 1.Chernyshevskii Saratov State UniversityUSSR

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