Chemistry of Heterocyclic Compounds

, Volume 1, Issue 2, pp 128–129 | Cite as

Investigation of furan compounds XXX. Intramolecular alkoxylation of furfuryl-substituted mono- and bicyclic alcohols

  • A. A. Ponomarev
  • I. A. Markushina


On electrolysis mono- and bicyclic furfuryl-substituted alcohols undergo intramolecular alkoxylation, giving polycyclic spirans. Spiro[perhydrobenzofuran-2, 2-(5′-methoxy, 5′H)furan] and spiro[4H, 5H, 6H, 11H-naphtho-(α,β)-furan-2(3H)] [2′-(5′-methoxy, 5′H)furan], hitherto not described, are prepared in this way. On catalytic hydrogenation they give the previously unknown spiro[perhydrobenzofuran-2, 2′-tetrahydrofuran] and spiro[4H, 5H, 6H, 11H-naphtho-(α,β)-furan-2(3H)][2′-tetrahydrofuran].


Hydrogenation Alcohol Organic Chemistry Methoxy Furan 
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Copyright information

© The Faraday Press, Inc. 1966

Authors and Affiliations

  • A. A. Ponomarev
    • 1
  • I. A. Markushina
    • 1
  1. 1.Chernyshevskii Saratov State UniversityUSSR

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