Advertisement

Chemistry of Heterocyclic Compounds

, Volume 5, Issue 1, pp 42–45 | Cite as

Synthesis and spectroscopic investigation of some arylazo derivatives of thiazolidin-4-one

  • I. I. Chizhevskaya
  • M. I. Zavadskaya
  • N. N. Khovratovich
Article
  • 40 Downloads

Abstract

The reaction of 2-phenylimino- and 2-(p-tolylimino)thiazolidin-4-ones with benzene-, p-nitrobenzene, p-sulfamoylbenzene-, and p-toluenediazonium chlorides in glacial acetic acid in the presence of anhydrous sodium acetate (pH of the medium 4.5–5.0) has been studied. A spectroscopic investigation in the IR and UV regions has shown that the 5-(p-nitrophenylazo) derivatives of thiazolidin-4-one exist in the azo tautomeric form; the 5-phenylazo and p-tolylazo derivatives of thiazolidin-4-one are mixtures of the azo and hydrazone tautomers.

Keywords

Sodium Acetate Chloride Benzene Acetic Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    F. C. Brown, Chem. Rev.,61, 463, 1961.Google Scholar
  2. 2.
    B. K. Patnaik and M. K. Rout, J. Indian Chem. Soc.,32, 563, 1955.Google Scholar
  3. 3.
    J. N. Mohapatra and M. K. Rout, J. Indian Chem. Soc.,33, 17, 1956.Google Scholar
  4. 4.
    B. K. Patnaik and M. K. Rout, J. Indian Chem. Soc.,34, 814, 1957.Google Scholar
  5. 5.
    I. I. Chizhevskaya, L. I. Gapanovich, and L. V. Poznyak, ZhOKh,33, 945, 1963.Google Scholar
  6. 6.
    A. A. Kharkharov, Dissertation [in Russian], Leningrad, p. 467, 1955.Google Scholar
  7. 7.
    A. Burawoy and A. R. Thompson, J. Chem. Soc., 1443, 1953.Google Scholar
  8. 8.
    P. F. Holt and A. E. Smith, J. Chem. Soc., 5245, 1965.Google Scholar
  9. 9.
    S. N. Baranov and A. N. Grishchuk, ZhOKh,32, 1938, 1962.Google Scholar
  10. 10.
    A. N. Grishchuk and S. N. Baranov, ZhOKh,28, 896, 1958.Google Scholar

Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • I. I. Chizhevskaya
    • 1
  • M. I. Zavadskaya
    • 1
  • N. N. Khovratovich
    • 1
  1. 1.Institute of Physical Organic Chemistry AS Belorussian SSRBelorussian State UniversityMinsk

Personalised recommendations