Abstract
An x-ray structural study has shown that 6-(3′-oxo-5′,5′-dimethyl-δ1′-pyrrolin-3′-yl)methylidene-2,2,7, 7-tetramethyl-4-hydroxybicyclo[2.2.2]azaoctane is formed as a low-molecular-weight byproduct of the solid-phase polymerization of 1,4-bis(2,2,6,6-tetramethyl-4-hydroxy-4-piperidyl)butadiyne.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
G. A. Vinogradov, Usp. Khim.,53, 135 (1984).
V. M. Misin and M. I. Cherkashin, Usp. Khim.,54, 956 (1985).
B. A. Frenz, in: Computing in Crystallography, H. Schenk, R. Olthof-Haselkamp, et al. (eds.), Univ. Press, Delft, Holland (1978), p. 64.
H. G. Viehe (ed.), Chemistry of Acetylenes, Dekker, New York (1969).
A. J. Bondi, Phys. Chem.,68, 441 (1964).
F. H. Allen, O. Kennard, D. G. Watson, et al., J. Chem. Soc. Dalton Trans. 2, 1 (1987).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 585–587, March, 1990.
Rights and permissions
About this article
Cite this article
Shklover, V.E., Struchkov, Y.T., Medvedeva, T.V. et al. Crystal and molecular structure of 1-aza-6′-(3′-oxo-5′, 5′-dimethyl-δ1′-pyrrolin-3′-yl)methylidene-2,2,7,7-tetramethyl-4-hydroxybicyclo-[2.2.21azaoctane. Russ Chem Bull 39, 508–510 (1990). https://doi.org/10.1007/BF00959572
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00959572