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The diene synthesis with sulfur-containing derivatives of acrylic acids

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Reaction of aqueous solutions of salts of acrylic acids with thioepi chlorohydrin affords thietyl acrylates, which on hydrolysis give 3-hydroxythietane, and on oxidation with hydrogen peroxide give 3-hydroxythietane 1,1-dioxide. The diene synthesis was carried out with these acrylates, and also with acryloyl and methacryloyl isothiocyanates.

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Authors and Affiliations

  1. State Associated Scientific Research Institute for Chloro-organic Compounds and Acrylates, Dzerzhinsk

    V. S. Étlis, L. N. Grobov & A. P. Sineokov

Authors
  1. V. S. Étlis
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  2. L. N. Grobov
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  3. A. P. Sineokov
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Additional information

The authors thanks M. I. Mironova for the IR spectra and the elemantal analyses.

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Étlis, V.S., Grobov, L.N. & Sineokov, A.P. The diene synthesis with sulfur-containing derivatives of acrylic acids. Chem Heterocycl Compd 5, 590–593 (1969). https://doi.org/10.1007/BF00957365

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  • DOI: https://doi.org/10.1007/BF00957365

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