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Reactions of cyclammonium cations

XXVIII. 4,9-Diazapyrene in hetarylation reactions

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The π-electron charges, bond orders, energies of the singlet and triplet electronic transitions, and the PMR spectrum of 4,9-diazapyrene were calculated by the self-consistent-field (SCF) method with allowance for the coulombic repulsion, and the results are compared with the experimentally found positions of the long-wave bands in the UV spectrum and the experimental PMR spectrum. 4,9-Diazapyrene hetarylates activated aromatic and heteroaromatic rings.

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Authors and Affiliations

  1. Donetsk Physical-Organic Chemistry Branch, Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Donetsk State University, USSR

    A. K. Sheinkman, M. M. Mestechkin, A. P. Kucherenko, V. V. Artemova, V. N. Poltavets & Yu. B. Vysotskii

Authors
  1. A. K. Sheinkman
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  2. M. M. Mestechkin
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  3. A. P. Kucherenko
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  4. V. V. Artemova
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  5. V. N. Poltavets
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  6. Yu. B. Vysotskii
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Additional information

See [1] for communication XXVII.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 537–541, April, 1974.

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Sheinkman, A.K., Mestechkin, M.M., Kucherenko, A.P. et al. Reactions of cyclammonium cations. Chem Heterocycl Compd 10, 466–470 (1974). https://doi.org/10.1007/BF00945643

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  • DOI: https://doi.org/10.1007/BF00945643

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