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Spectroscopic study of organosilicon derivatives of thiophene

V. IR spectra of mono- and disubstituted thiophenes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The IR spectra of organosilicon derivatives of thiophene were investigated. A comparison of the results with the literature data made it possible to isolate the characteristic absorption bands of the substituted thiophene ring and to reveal some regularities in the IR spectra of thienylsilanes. Theσ inductive constants of substituted thienyl groups

were calculated from the experimentalΝ(Si-Cl) values. An analysis of theσ values shows that electron-donor substituents X lower the acceptor capacity of the thienyl substituent as a whole, while electron-acceptor substituents increase it.

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Literature cited

  1. A. N. Egorochkin, N. S. Vyazankin, A. I. Burov, E. A. Chernyshev, V. I. Savushkina, and O. V. Kuz' min, Khim. Geterotsikl. Soedin., 1483 (1972).

  2. Ya. M. Kimel'fel'd, V. T. Aleksanyan, N. N. Magdesieva, and Yu. K. Yur'ev, Zh. Strukt. Khim.,7, 42 (1966).

    Google Scholar 

  3. M. Horak, I. J. Hyams, and E. R. Lippingott, Spectrochim. Acta,22, 1355 (1966).

    Google Scholar 

  4. J. J. Peron, P. Saumagne, and J. M. Lebars, Spectrochim. Acta,26A, 1651 (1970).

    Google Scholar 

  5. M. Rico, J. M. Orza, and J. Morcillo, Spectrochim. Acta,21, 689 (1965).

    Google Scholar 

  6. V. T. Aleksanyan, Ya. M. Kimel'fel'd, N. N. Magdesieva, and Yu. K. Yur'ev, in: Optics and Spectroscopy [in Russian], Vol. 3, Nauka, Leningrad (1967), p. 168.

    Google Scholar 

  7. A. Minori and K. Yuzo, J. Mol. Spectr.,34, 288 (1970).

    Google Scholar 

  8. A. D. Petrov, Yu. P. Egorov, V. F. Mironov, G. I. Nikishin, and A. A. Bugorkova, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 50 (1956).

  9. N. N. Vyshinskii, Master's Dissertation [in Russian], Gor'kii (1963).

  10. S. E. Rudakova, Master's Dissertation [in Russian], Moscow (1965).

  11. N. A. Chumaevskii, Vibrational Spectra of Heteroorganic Compounds of Group IVB and VB Elements [in Russian], Nauka, Moscow (1971).

    Google Scholar 

  12. L. A. Leites, I. D. Pavlova, and Yu. P. Egorov, Teor. i éksperim. Khim.,1, 311 (1965).

    Google Scholar 

  13. H. Kriegsmann, Allg. Prakt. Chem.,19, 5 (1968).

    Google Scholar 

  14. P. A. Ten, Thije, and M. A. Janssen, Rec. Trav. Chim.,84, 1169 (1965).

    Google Scholar 

  15. A. N. Egorochkin, N. S. Vyazankin, A. I. Burov, and S. Ya. Khorshev, Izv. Akad. Nauk SSSR, Ser. Khim., 1272 (1970).

  16. A. N. Egorochkin, S. Ya. Khorshev, N. S. Vyazankin, T. I. Chernyshev, and O. V. Kuz'min, Izv. Akad. Nauk SSSR, Ser, Khim., 544 (1971).

  17. A. N. Egorochkin, S. Ya. Khorshev, N. S. Vyazankin, T. I. Chernysheva, and O. V. Kuz'min, Izv. Akad. Nauk SSSR, Ser. Khim., 776 (1971).

  18. A. N. Egorochkin, N. S. Vyazankin, A. I. Burov, E. A. Chernyshev, V. I. Savushkina, and B. M. Tabenko, Khim. Geterotsikl. Soedin., 911 (1972).

  19. A. N. Egorochkin, N. S. Vyazankin, S. E. Skobeleva, S. Ya. Khorshev, E. A. Chernyshev, V. I. Savushkina, and O. V. Kuz'min, Khim. Geterotsikl. Soedin., 1057 (1972).

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSR, Gor'kii

    S. Ya. Khorshev, N. S. Vyazankin, A. N. Egorochkin, E. A. Chernyshev, V. I. Savushkina, O. V. Kuz'min & V. Z. Anisimova

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  1. S. Ya. Khorshev
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  2. N. S. Vyazankin
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  3. A. N. Egorochkin
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  4. E. A. Chernyshev
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  5. V. I. Savushkina
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  6. O. V. Kuz'min
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  7. V. Z. Anisimova
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Additional information

See [1] for communication IV.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 477–481, April, 1974.

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Khorshev, S.Y., Vyazankin, N.S., Egorochkin, A.N. et al. Spectroscopic study of organosilicon derivatives of thiophene. Chem Heterocycl Compd 10, 413–417 (1974). https://doi.org/10.1007/BF00945629

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  • DOI: https://doi.org/10.1007/BF00945629

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