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Iodocyclization of N, N-dialkylamino-2-methyl-4-penten-2-ol oxides

I. Reaction products

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

It is shown that in the iodination of N,N-dialkylamino-2-methyl-4-penten-2-ol and N,N-diethylamino-3-butene oxides the N-oxide group participates in the intramolecular cyclization of these compounds. N,N-Dialkyl-4-methyl-4-hydroxy-6-iodomethyltetrahydro-1,2-oxazine iodides were obtained by iodination of the former, whereas the latter under similar conditions gives N,N-diethyl-5-iodomethyltetrahydro-1,2-oxazolinium iodide.

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Literature cited

  1. V. I. Staninets and E. A. Shilov, Usp. Khim.,40, 491 (1971).

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    Yu. I. Gevaza, V. I. Staninets & É. B. Koryak

Authors
  1. Yu. I. Gevaza
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  2. V. I. Staninets
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  3. É. B. Koryak
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1340–1343, October, 1976.

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Gevaza, Y.I., Staninets, V.I. & Koryak, É.B. Iodocyclization of N, N-dialkylamino-2-methyl-4-penten-2-ol oxides. Chem Heterocycl Compd 12, 1111–1114 (1976). https://doi.org/10.1007/BF00945591

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  • DOI: https://doi.org/10.1007/BF00945591

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