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Research on furan acetal compounds

IX. Isomerization of 4-alkyl-2-(5′-x-2′-furyl)-1,3-dioxolanes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

When 4-alkyl-2-(5′-X-2′-furyl)-1,3-dioxolanes are heated in the presence of tert-butyl peroxide the acetal ring is opened at the C-O 3–4 bond to give isomeric esters of 5-substituted furan-2-carboxylic acid. The structure of the product was confirmed by means of the UV and IR spectra, gas-liquid chromatography, and alternative synthesis.

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Authors and Affiliations

  1. Krasnodar Polytechnic Institute, USSR

    V. G. Kul'nevich, Z. I. Zelikman & S. E. Tkachenko

Authors
  1. V. G. Kul'nevich
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  2. Z. I. Zelikman
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  3. S. E. Tkachenko
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Additional information

See [1] for communication VIII.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1327–1329, October, 1976.

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Kul'nevich, V.G., Zelikman, Z.I. & Tkachenko, S.E. Research on furan acetal compounds. Chem Heterocycl Compd 12, 1100–1102 (1976). https://doi.org/10.1007/BF00945587

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  • DOI: https://doi.org/10.1007/BF00945587

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