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Atranes

XLII. Kinetics of the hydrolysis of 1-alkoxy- and 1-aryloxysilatranes

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The hydrolysis of silatranes of the

: type (R=alkyl, aryl) in the presence of HCl at 25°C is described by a second-order kinetic equation. The correlation dependence of the log k values on the σ *OR values makes it possible to divide the investigated compounds into two reaction series — 1-alkoxy- and 1-aryloxysilatranes. An investigation of the potentiometric curves and the change in the acid functions of the media during the hydrolysis of the silatranes made it possible to propose a scheme for the mechanism of this reaction. The linear dependence of the v values on [HCl] provides evidence that noncatylic hydrolysis of the silatranes practically does not occur under the investigated conditions. A salt effect is not manifested during the hydrolysis of the silatranes (at KCl concentrations from 0.05 to 0.25 mole/liter). The toxicity of the 1-aryloxysilatranes is basically reduced as their rate of hydrolytic cleavage increases.

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Literature cited

  1. M. G. Voronkov, V. M. D'yakov, G. A. Samsonova, Yu. A. Lukina, and N. M. Kudyakov, Izv. Akad. Nauk SSSR, Ser. Khim., 2794 (1974).

  2. M. G. Voronkov and G. I. Zelchan, Khim. Geterotsikl. Soedin., 450 (1969).

  3. S. Benson, Foundations of Chemical Kinetics, McGraw-Hill (1960).

  4. Chemist's Handbook [in Russian], Vol. 3, Khimiya, Leningrad (1964), p. 955.

  5. V. A. Palm, Fundamentals of the Quantitative Theory of Organic Reactions [in Russian], Khimiya, Leningrad (1967).

    Google Scholar 

  6. G. I. Zelchan, Master's Dissertation, Riga (1967).

  7. V. A. Chetverikova, V. A. Kogan, G. I. Zelchan, M. G. Voronkov, and O. A. Osipov, Khim. Geterotsikl. Soedin., 446 (1969).

  8. Experimental Methods of Chemical Kinetics [in Russian], Vysshaya Shkola, Moscow (1971), p. 31.

  9. M. L. Belen'kii, Elements of the Quantitative Evaluation of Pharmacological Effects [in Russian], Leningrad (1963), p. 23.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    M. G. Voronkov, I. S. Emel'yanov, G. I. Zelchan, V. M. D'yakov & I. G. Kuznetsov

  2. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, Riga

    M. G. Voronkov, I. S. Emel'yanov, G. I. Zelchan, V. M. D'yakov & I. G. Kuznetsov

Authors
  1. M. G. Voronkov
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  2. I. S. Emel'yanov
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  3. G. I. Zelchan
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  4. V. M. D'yakov
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  5. I. G. Kuznetsov
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Additional information

See [1] for communication XLI.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 35–39, January, 1975.

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Voronkov, M.G., Emel'yanov, I.S., Zelchan, G.I. et al. Atranes. Chem Heterocycl Compd 11, 28–31 (1975). https://doi.org/10.1007/BF00945265

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  • DOI: https://doi.org/10.1007/BF00945265

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