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Atranes

XXXIII. PMR spectra of metalloatrane-3,7,10-triones containing a group-IIIB metal atom

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The PMR spectra of acidified solutions of metalloatrane-3,7,10-trione dihydrates

containing a group-IIIB metal atom (M=Al, Ga, In, Tl) in D2O were studied. The equivalence of the three atrane half-rings in all of the investigated molecules and of the methylene protons in each half-ring was proved. Spin-spin coupling of203Tl and205Tl with protons, which is apparently realized through a Tl←N transannular coordinate bond, is observed in the PMR spectrum of thallatrane-3,7,10-trione (M=Tl). The factors that determine the magnitudes of the chemical shifts of the methylene protons are discussed.

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Literature cited

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Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, Riga

    M. G. Voronkov, V. A. Pestunovich, S. V. Mikhailova, Yu. Yu. Popelis & É. É. Liepin'sh

  2. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    M. G. Voronkov, V. A. Pestunovich, S. V. Mikhailova, Yu. Yu. Popelis & É. É. Liepin'sh

Authors
  1. M. G. Voronkov
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  2. V. A. Pestunovich
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  3. S. V. Mikhailova
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  4. Yu. Yu. Popelis
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  5. É. É. Liepin'sh
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Additional information

See [1] for communication XXXII.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 312–314, March, 1973.

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Voronkov, M.G., Pestunovich, V.A., Mikhailova, S.V. et al. Atranes. Chem Heterocycl Compd 9, 286–288 (1973). https://doi.org/10.1007/BF00944495

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  • DOI: https://doi.org/10.1007/BF00944495

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