Skip to main content
SpringerLink
Log in

Synthesis and some transformations of thiophene series sulfides

XIII. Structure of the compound of formula C10H7NS4 obtained from sodium 2-diethoxymethyl-3-thienylmercaptide

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The compound of formula C10H7N84, formed by the reaction of sodium-2-diethoxymethyl-3-thienylmercaptide with ammonia followed by acidification to pH 8 [1], is evidently bis(3-thiono-2-thienylidene)-dimethylamine (Ia). The action of primary amines on the thienylidenamine Ia gives N-substituted 3-mercapto-2-thienylidenimines (XIIa-c). With nickel acetate the azomethine XIIa forms an intramolecular complex (XIII).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, KhGS [Chemistry of Heterocyclic Compounds], 62, 1967.

  2. R. Mecke, R. Mecke, and A. Lüttringhaus, Z. Naturforsch.,10b, 367, 1955.

    Google Scholar 

  3. A. B. Turner, Quart. Rev.,18, 358, 1964.

    Google Scholar 

  4. S. Gronowitz, Ark. kemi,13, 269, 1958.

    Google Scholar 

  5. Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, Izv. AN SSSR, OKhN, 701, 1967.

  6. K. Koehler, W. Sandstrom, and E. H. Cordes, J. Am. Chem. Soc.,86, 2413, 1964.

    Google Scholar 

  7. Ya. L. Gol'dfarb, M. A. Kalik, and M. L. Kirmalova, Izv. AN SSSR, ser. khim., 897, 1966.

Download references

Author information

Authors and Affiliations

  1. Zelinskii Institute of Organic Chemistry, AS USSR, Moscow

    Ya. L. Gol'dfarb, M. A. Kalik & M. L. Kirmalova

Authors
  1. Ya. L. Gol'dfarb
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. A. Kalik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. L. Kirmalova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

For Part XII see [1].

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gol'dfarb, Y.L., Kalik, M.A. & Kirmalova, M.L. Synthesis and some transformations of thiophene series sulfides. Chem Heterocycl Compd 3, 50–53 (1967). https://doi.org/10.1007/BF00944257

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00944257

Keywords

Search

Navigation