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Synthesis of hydrothioxanthenes

VIII. Reaction of alkyledenedicyclohexanones with phosphorus pentasulfide

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Alkylidenedicyclohexanones I–III react with phosphorus pentasulfide in an inert solvent to form sym-octahydrothioxanthenes, which, under the influence of the acid products of the decomposition of phosphorus pentasulfide, are converted to perhydrothioxanthenes and sym-octahydrothioxanthylium salts.

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See [1] for communication VII.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1196–1199, September, 1972.

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Kharchenko, V.G., Krupina, T.I., Klimenko, S.K. et al. Synthesis of hydrothioxanthenes. Chem Heterocycl Compd 8, 1081–1084 (1972). https://doi.org/10.1007/BF00944218

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  • DOI: https://doi.org/10.1007/BF00944218

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