Abstract
UV irradiation causes no acceleration of the oxidation of furfural by hydrogen peroxide but maintains its occurrence at a uniform rate. Both with UV irradiation and without it, the oxidation of furfural by hydrogen peroxide takes place via the formation of intermediate peroxide compounds, with their subsequent conversion mainly into a mixture of β-formylacrylic, maleic, and succinic acids. The ratio between the acids depends on the reaction conditions. The possibility has been shown of a directed oxidation to β-formylacrylic acid.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. P. Dunlop and F. N. Peters, The Furans, New York, 385, 1953.
Yu. I. Khol'kin, Thesis [in Russian], Krasnoyarsk, p. 148, 1961.
M. V. Tarvid, Thesis [in Russian], Riga, 1952.
C. F. Cross, E. G. Bevan, and T. Heiberg, J. Chem. Soc.,75, 747, 1899.
F. Kallay, Acta Chim. Acad. Sci. Hung.,10, 157, 1957.
L. P. Salchinkin, VIIIth Mendeleev Conference on General and Applied Chemistry [in Russian], Izd-vo AN SSSR, Moscow, p. 335, 1959.
M. P. Pyatnitskii and L. B. Lapkova, Trudy Krasnodarsk. ped. inst., Krasnodar,27, 25, 1962.
L. B. Lapkova, Thesis [in Russian], Krasnodar, 1963.
L. B. Lapkova and V. G. Kul'nevich, Collection of Lectures at a Conference on the Results of Scientific Research Work in 1964, Vol. 2 [in Russian], KPI, Krasnodar, p. 43, 1965.
G. O. Schenck, Angew. Chem.,64, 12, 1952.
V. Franzen and L. Fikentscher, Ann.,623, 68, 1959.
K. Alder and F. Farina, Ann. real. soc. españ. fis. quim.,54B, 689, 1958; C.,132, 8643, 1961.
W. Waters, Chemistry of Free Radicals [Russian translation], IL, Moscow, p. 268, 1948.
W. Schumb, C. Satterfield, and R. Wentworth, Hydrogen Peroxide [Russian translation], IL, Moscow p. 85, 1958.
V. I. Kondrat'ev, Free Radicals — Active Forms of Matter [in Russian], Izd-vo AN SSSR, Moscow, pp. 18, 24, 1960.
T. E. Goldovskaya and V. G. Kul'nevich, Izv. VUZ. Pishchev. tekhnol., 5, 205, 1965.
L. A. Badovskaya, V. N. Vasyukova, and V. G. Kul'nevich, ZhAKh, 22, 1289, 1967.
L. A. Badovskaya and V. G. Kul'nevich, ZhAKh,22, 272, 1967.
Organic Electronic Spectral Data,1, 41, 1960.
E. N. E. Hellström, Kgl. Lantbruks-Högskol. Ann.,23, 519, 1957.
Dictionary of Organic Compounds, Vol. 2 [Russian translation], IL, Moscow, p. 90, 1949.
H. Meyer, Analyse und Konstitutionsermittlung organischer Verbindungen [Russian translation], ONTI, Moscow, p. 145, 1937.
The Analytical Chemistry of Polymers [Russian translation], IL, Moscow, p. 31, 1963.
V. G. Kul'nevich and L. A. Badovskaya, USSR patent no. 195 447, 1966; Byull. izobr., no. 10, 1967.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Badovskaya, L.A., Kul'nevich, V.G. Influence of the reaction conditions on the nature of the hydrogen peroxide oxidation products of furfural. Chem Heterocycl Compd 5, 146–150 (1969). https://doi.org/10.1007/BF00943897
Issue Date:
DOI: https://doi.org/10.1007/BF00943897