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Reaction of 3-aryl-2-benzoyloxiranes with alkyl thiocyanates

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

3-Aryl-2-benzoyloxiranes and alkyl thiocyanates in the presence of an equivalent amount of anhydrous AlCl3 form erythro-N-(2-benzoyl-l-aryl-2-chloroethyl)-S-alkyl thiocarbamates and α-diketones. p-Toly1- and p-anisy1-2-benzoy1-oxiranes do not react with alkyl thiocyanates, but isomerize to the respective α-diketones, and form the threo-chlorohydrins in low yield.

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Authors and Affiliations

  1. V. I. Lenin Belorussian State University, 220080, Minsk

    O. N. Bubel', I. G. Tishchenko & O. A. Grinkevich

Authors
  1. O. N. Bubel'
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  2. I. G. Tishchenko
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  3. O. A. Grinkevich
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Translated from Khimiya Geterotsilklicheskikh soedinenii, No. 12, pp. 1624–1628, December, 1985.

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Bubel', O.N., Tishchenko, I.G. & Grinkevich, O.A. Reaction of 3-aryl-2-benzoyloxiranes with alkyl thiocyanates. Chem Heterocycl Compd 21, 1335–1338 (1985). https://doi.org/10.1007/BF00842955

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  • DOI: https://doi.org/10.1007/BF00842955

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