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Chemistry of Heterocyclic Compounds

, Volume 15, Issue 5, pp 531–534 | Cite as

Chemistry of heterocyclic N-oxides and related compounds. 11. Reaction of pyridine N-oxide with metal ketyls and benzophenone dianions

  • A. S. Kurbatova
  • Yu. V. Kurbatov
  • D. A. Niyazova
Article

Abstract

The reaction of pyridine N-oxide with metal ketyls of benzophenone was studied. It is shown that diphenyl(2-pyridyl)carbinol N-oxide is formed with the lithium and sodium derivatives of benzophenone, whereas diphenyl(2-pyridyl)carbinol is formed with the potassium derivative of benzophenone. Diphenyl(2-pyridyl)carbinol N-oxide is obtained in lower yields in the reaction of pyridine N-oxide with benzophenone dianions. Pyridine and 4,4′- and 2,2′-dipyridyls are simultaneously formed in all of the reactions.

Keywords

Sodium Potassium Lithium Organic Chemistry Pyridine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • A. S. Kurbatova
    • 1
  • Yu. V. Kurbatov
    • 1
  • D. A. Niyazova
    • 1
  1. 1.A. Navoi Samarkand State UniversitySamarkand

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