Abstract
The mass spectra of stereoisomeric derivatives of 4-hydroxypiperidines obtained at various ionizing-electron energies with the application of isotopic substitution and high-resolution mass spectrometry are examined. The character of the fragmentation of the piperidine ring as a function of the position and spatial orientation of the substituent is discussed.
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Communication VI from the series “Applications of Mass Spectrometry in Structural and Stereochemical Investigations.” See [1] for communication V.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1647–1655, December, 1975.
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Ermakov, A.I., Sheinker, Y.N., Torosyan, Z.K. et al. Mass spectra and three-dimensional structure of 4-hydroxypiperidine derivatives. Chem Heterocycl Compd 11, 1395–1401 (1975). https://doi.org/10.1007/BF00764534
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DOI: https://doi.org/10.1007/BF00764534