Abstract
The corresponding stereoisomeric p-nitrobenzoates were obtained by reaction of the geometrical isomers of 1,3-dimethyl-, 1,2,5-trimethyl-, and 1-tert-butyl-3-methyl-4-hydroxypiperidines with p-nitrobenzoyl chloride. The stereoisomers of the corresponding benzoates were also synthesized from the geometrical isomers of 1,3-dimethyl-4-hydroxypiperidines. The primary conformations of the investigated compounds in solution were established by means of their PMR spectra.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
K. I. Romanova, S. V. Bogatkov, T. D. Sokolova, Yu. F. Malina, and B. V. Unkovskii, Reakts. Sposobnost' Organ. Soedin.,9, 93 (1972).
T. D. Sokolova, Yu. V. Kolosov, Yu. F. Malina, S. V. Bogatkov, and B. V. Unkovskii, Khim. Geterotsikl. Soedin., 50 (1973).
N. N. Bolyard and S. M. McElvain, J. Amer. Chem. Soc.,51, 922 (1929).
B. V. Unkovskii, Yu. F. Malina, T. D. Sokolova, S. I. Gavrilova, K. I. Romanova, and Yu. V. Kolosov, Khim. Geterotsikl. Soedin., 1056 (1973).
É. A. Mistryukov, Izv. Akad. Nauk SSSR, Ser. Khim., 1826 (1965).
I. I. Nazarov, D. V. Sokolov, V. N. Rakcheeva, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 80 (1954).
N. Bhacca and D. Williams, Applications of NMR Spectroscopy in Organic Chemistry, Holden-Day (1964).
B. I. Ionin and B. A. Ershov, Nuclear Magnetic Spectroscopy in Organic Chemistry [in Russian], Khimiya. Leningrad (1967), p. 221.
Author information
Authors and Affiliations
Additional information
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1643–1646, December, 1975.
Rights and permissions
About this article
Cite this article
Sokolova, T.D., Romanova, K.I., Malina, Y.F. et al. Synthesis and three-dimensional structure of the benzoates and p-nitrobenzoates of the geometrical isomers of substituted 4-hydroxypiperidines. Chem Heterocycl Compd 11, 1391–1394 (1975). https://doi.org/10.1007/BF00764533
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00764533