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Addition of thiophenols to N-vinylpyrroles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Thiophenols add to 1-vinyl-4,5,6,7-tetrahydroindole and 1-vinyl-2-phenylpyrrole in the presence of azobisisobutyronitrile to form 1-(2-arylthioethyl)pyrroles. The major products in the absence of initiator are the isomeric 1-(1-arylthioethyl)pyrrole α-adducts. NH-Pyrroles inhibit the radical process and form selectively the α-adducts.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, 664033, Irkutsk

    I. A. Aliev, A. I. Mikhaleva & B. R. Gasanov

  2. S. M. Kirov State University, 370073, Baku

    I. A. Aliev, A. I. Mikhaleva & B. R. Gasanov

Authors
  1. I. A. Aliev
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  2. A. I. Mikhaleva
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  3. B. R. Gasanov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 750–752, June, 1990.

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Aliev, I.A., Mikhaleva, A.I. & Gasanov, B.R. Addition of thiophenols to N-vinylpyrroles. Chem Heterocycl Compd 26, 624–627 (1990). https://doi.org/10.1007/BF00756411

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  • DOI: https://doi.org/10.1007/BF00756411

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