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Synthesis of esters of 5-oxo-3-oxapentanecarboxylic acids and their cyclization to give homologs of dioxanone and morpholinone

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

By hydrogenating methyl esters of 4-furyl-3-oxapropanecarboxylic acids on Pt-C we have obtained the corresponding esters of 5-oxo-3-oxapentanecarboxylic acids and have converted these under the conditions of reductive animation into the corresponding homologs of morpholin-3-one and by reduction in an alkaline medium into homologs of 1,4-dioxan-2-one.

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Authors and Affiliations

  1. Zelinskii Institute of Organic Chemistry, AS USSR, USSR

    S. N. Khar'kov, V. M. Shostakovskii & I. F. Bel'skii

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  1. S. N. Khar'kov
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  2. V. M. Shostakovskii
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  3. I. F. Bel'skii
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Khar'kov, S.N., Shostakovskii, V.M. & Bel'skii, I.F. Synthesis of esters of 5-oxo-3-oxapentanecarboxylic acids and their cyclization to give homologs of dioxanone and morpholinone. Chem Heterocycl Compd 4, 306–307 (1968). https://doi.org/10.1007/BF00755264

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  • DOI: https://doi.org/10.1007/BF00755264

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