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Preparation of sydnoneimines by basic cyclization of N-nitrosoaminoacetonitriles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The results of a kinetic study of the cyclization of N-nitrosoaminoacetonitriles in the presence of tertiary amines are presented. The dependence of the reaction rate on the character of the substituents attached to the nitrogen atom in the starting N-nitrosoaminoacetonitrile, concentration and temperature dependences, and the effect of solvents were established.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1244–1247, September, 1980.

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Yashunskii, V.G., Ogorodnikova, V.V. & Kholodov, L.E. Preparation of sydnoneimines by basic cyclization of N-nitrosoaminoacetonitriles. Chem Heterocycl Compd 16, 941–945 (1980). https://doi.org/10.1007/BF00742842

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  • DOI: https://doi.org/10.1007/BF00742842

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