Some fundamental difficulties with quantum mechanical collision theory

Abstract

When quantum scattering theory is applied strictly from the point of view that the state of a system is completely described by the density matrix, whether pure or mixed, it is not possible to assume that colliding particles are at all times individually in pure states. Exact results are significantly different from conventionally accepted approximations. In particular, it turns out that the cross section as ordinarily defined in theS-matrix formalism is an adequate parameter for deciding the outcome of interactions only when the particles are carefully prepared in matching pure states. In general the use of the cross section in studying pair collisions in a real gas is shown to be analogous to a repeated “collapse of the wave function” after each collision, and involves arbitrary removal of nondiagonal elements of the density matrix, thus violating the basic laws of quantum dynamical evolution.