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Recyclization reactions of heterocycles

XXI. Recyclization of azolidones to benzimidazole derivatives

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

2-Thioxo-4-oxazolidone and thiazolidines containing heteroatom substituants (O, S, and NH) in the 2 and 4 positions are converted to benzimidazole derivatives on reaction with o-phenylenediamine. The direction of these recyclizations depends on the nature of the heteroatom substituents in the 2 and 4 positions of the heteroring.

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See [1] for communication XX.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 666–668, May, 1978.

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Lipnitskii, V.F., Shvaika, O.P., Fomenko, V.I. et al. Recyclization reactions of heterocycles. Chem Heterocycl Compd 14, 547–549 (1978). https://doi.org/10.1007/BF00673341

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  • DOI: https://doi.org/10.1007/BF00673341

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