Abstract
2-Acetimido-4-chloro-2H-1-thiochromene, in which the chlorine atom is exchanged by hydroxy and amino groups, was synthesized by the action of phosphorus oxychloride on 2-acetamido-1-thiochromone. It was established on the basis of the IR, UV, PMR, and mass spectra that the product of the reaction of this compound with aniline has the 2-acetaraido-1-thiochromene structure.
Similar content being viewed by others
Literature cited
V. A. Zagorevskii, V. G. Vinokurov, and Sh. M. Glozman, Khim. Geteorsikl. Soedin., No. 2, 171 (1970).
L. A. Zhmurenko, Sh. M. Glozman, and V. A. Zagorevskii, Khim. Geterotsikl. Soedin., No. 2, 182 (1978).
V. A. Zagorevskii, Sh. M. Glozman, V. G. Vinokurov, and V. S. Troitskaya, Khim. Geterotsikl. Soedin., No. 5, 782 (1967).
Yu. N. Sheinker, Tr. Vses. Nauch.-issled. Khim.-Farm. Inst., No. 2, 210 (1971).
M. I. Kabachnik, Zh. Vses. Khim. Ob-va,7, 263 (1962).
W. Asker, M. Enagdi, and S. M. Fahmy, J. Prakt. Chem.,313, 715 (1971).
Sh. M. Glozman, L. A. Zhmurenko, and V. A. Zagorevskii, Khim.-Farm. Zh., No. 5, 17 (1971).
P. I. Zakharov, Zh. Org. Khim.,7, 383 (1971).
L. Bellamy, New Data on the IR Spectra of Complex Molecules [Russian translation], Mir, Moscow (1971).
Sh. M. Glozman, D. V. Zagorevskii, L. A. Zhmurenko, and V. A. Zagorevskii, Khim. Geterotsikl. Soedin., No. 11, 1477 (1976).
Author information
Authors and Affiliations
Additional information
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 622–625, May, 1978.
Rights and permissions
About this article
Cite this article
Glozman, O.M., Zhmurenko, L.A. & Zagorevskii, V.A. Conversion of 2-acetamido-1-thiochromone to the corresponding 4-chloro and 4-amino derivatives. Chem Heterocycl Compd 14, 507–511 (1978). https://doi.org/10.1007/BF00673333
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00673333