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Reaction of dibenzoylfuroxane with primary aliphatic amines and methylhydrazine

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Mixtures of products of the reaction of dibenzoylfuroxane with isopropylamine, tert-butylamine, and methylhydrazine were separated by high-pressure liquid chromatography. According to the proposed reaction scheme, benzamidoglyoxime is formed in the first step, after which it undergoes cyclization to give an N-substituted 3-amino-4-nitroso-5-phenylisoxazole or decomposes via the mechanism of a Beckmann rearrangement of the second type.

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Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga

    A. V. Eremeev, V. G. Andrianov & I. P. Piskunova

Authors
  1. A. V. Eremeev
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  2. V. G. Andrianov
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  3. I. P. Piskunova
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 616–619, May, 1978.

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Eremeev, A.V., Andrianov, V.G. & Piskunova, I.P. Reaction of dibenzoylfuroxane with primary aliphatic amines and methylhydrazine. Chem Heterocycl Compd 14, 503–505 (1978). https://doi.org/10.1007/BF00673331

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  • DOI: https://doi.org/10.1007/BF00673331

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