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Aryl 2-thienyl sulfides and aryl 2-thienyl sulfones

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A method was developed for the synthesis of the previously unknown aryl 2-thienyl sulfides; the method is based on the reaction of 2-chlorothiophene and its derivatives with thiophenols in the gas phase at 450–500°C. The synthesized sulfides were oxidized to the corresponding aryl 2-thienyl sulfones, which were also previously unknown. 2,5-Dichlorothiophene reacts with excess thiophenol to give 2,5-bis(phenylthio)thiophene, which is oxidized to the corresponding disulfone.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    M. G. Voronkov, É. N. Deryagina, L. G. Klochkova, E. A. Chernyshev, V. I. Savushkina & G. A. Kravchenko

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  1. M. G. Voronkov
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  2. É. N. Deryagina
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  3. L. G. Klochkova
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  4. E. A. Chernyshev
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  5. V. I. Savushkina
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  6. G. A. Kravchenko
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1322–1323, October, 1975.

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Voronkov, M.G., Deryagina, É.N., Klochkova, L.G. et al. Aryl 2-thienyl sulfides and aryl 2-thienyl sulfones. Chem Heterocycl Compd 11, 1131–1132 (1975). https://doi.org/10.1007/BF00667605

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  • DOI: https://doi.org/10.1007/BF00667605

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