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Perfluorinatedα-oxides

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Perfluorinatedα-oxides from perfluoropropene, perfluoroisobutene, and 8-hydroperfluorooctene are prepared by oxidizing the perfluoroolefins with alkaline hydrogen peroxide. It is shown that treatment with hydrogen halide acids, alcohols, and thiourea leads to scission of the C-O bond of theα -oxides at the ß-carbon atom. The products are a-bromoperfluorocarboxylic acids, esters ofα-alkoxyperfluorocarboxylic acids, and 2-amino-4-oxo-5-perfluoroalkylthiazolines.

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Knunyants, I.L., Shokina, V.V. & Galakhov, I.V. Perfluorinatedα-oxides. Chem Heterocycl Compd 2, 666–670 (1968). https://doi.org/10.1007/BF00664829

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  • DOI: https://doi.org/10.1007/BF00664829

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