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Chemistry of furanidine ketones

III. Some reactions of 4-Diazo-2, 2, 5, 5-tetramethylfuranid-3-one

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Catalytic cracking of 4-diazo-2, 2,5,5-tetramethylfuranid-3-one (I) in inert solvents gives the azine of 2, 2, 5,5-tetramethylfuranidine-3,4-dione (V), ketene dimer VI, and 2,2, 5, 5-tetramethylfuranidine-3,4-dione(VII). Treatment of diazoketone I with electrophilic reagents leads to replacement of the diazo group by hydroxyl and chlorine.

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Authors and Affiliations

  1. Zhdanov Leningrad State University, U.S.S.R.

    I. K. Korobitsyna, L. L. Rodina & L. M. Stashkova

Authors
  1. I. K. Korobitsyna
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  2. L. L. Rodina
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  3. L. M. Stashkova
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For Parts I and II, see [1,2]

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Korobitsyna, I.K., Rodina, L.L. & Stashkova, L.M. Chemistry of furanidine ketones. Chem Heterocycl Compd 2, 642–645 (1968). https://doi.org/10.1007/BF00664823

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  • DOI: https://doi.org/10.1007/BF00664823

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