Synthesis of 5-alkenyl-1,3-dioxanes
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Cyclic acetals containing alkenyl groups were obtained from 5-methyl-5-acyl-1,3-dioxane. The 1,3-dioxane fragment does not interfere in reduction of the carbonyl group, nor in participation of the carbonyl group in Wittig and Grignard reactions.
KeywordsAcetal Organic Chemistry Carbonyl Carbonyl Group Dioxane
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- 1.D. L. Rakhmankulof, R. A. Karakhanov, S. S. Zlotskii, E. A. Kantor, U. B. Imashev, and A. M. Syrkin, “Chemistry and technology of 1,3-dioxacyclanes,”Ref. Zh. Khim., Tekhnol. Org. Veshch.,5, 279 (1979).Google Scholar
- 2.D. L. Rakhmankulov, S. S. Zlotskii, M. G. Safarov, et al.,Mechanisms of Reactions of Acetals [in Russian], Khimiya, Moscow (1987), p. 292.Google Scholar
- 3.V. N. Saprygina, S. S. Zlotskii, and D. L. Rakhmankulov,Izv. Vyssh. Uchebn., Zaved., Khim. Khim. Tekhnol.,29, 110 (1986).Google Scholar
- 4.B. Wessen and L.-O. Ryrfors,Acta Chem. Scand.,22, 2071 (1968).Google Scholar