Chemistry of Natural Compounds

, Volume 22, Issue 5, pp 583–584 | Cite as

Alkaloids ofPetilium raddeana. V. Structure of petisidinone

  • A. Nabiev
  • R. Shakirov
  • S. Yu. Yunusov


From the epigeal part ofPetilium raddeana have been isolated the known alkaloids edpetiline and edpetine and the new base petisidinone with mp 217–219°C, [α]D 0° (c 0.169; chloroform), C27H39NO3 (I). When the known alkaloid petisidine was oxidized, a product identical with petisidinone (I) was obtained. Thus, the structure of (I) has been established as 26,23-nitrilocholestane-3,6,22-trione. Details of the IR, PMR, and mass spectra of (I) are given.


Alkaloid Mother Liquor Trione Sodium Sulfite Epigeal Part 

Literature cited

  1. 1.
    A. Nabiev, R. Shakirov, and U. T. Shakirova, Khim. Prir. Soedin., 405 (1981).Google Scholar
  2. 2.
    I. Nakhatov, A. Nabiev, and R. Shakirov, Khim. Prir. Soedin., 616 (1981).Google Scholar
  3. 3.
    A. Nabiev, I. Nakhatov, R. Shakirov, and S. Yu. Yunusov, Khim. Prir. Soedin., 528 (1982).Google Scholar
  4. 4.
    R. Shakirov and S. Yu. Yunusov, Khim. Prir. Soedin., 3 (1980).Google Scholar
  5. 5.
    R. N. Nuriddinov and S. Yu. Yunusov, Khim. Prir. Soedin., 603 (1969).Google Scholar
  6. 6.
    G. Kusano, T. Takemoto, V. Sato, and D. F. Johnson, Chem. Pharm. Bull.,24, 661 (1976).CrossRefGoogle Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • A. Nabiev
  • R. Shakirov
  • S. Yu. Yunusov

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