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Triterpenoids fromAbies species. I. Abiesonic acid — A triterpenoid with a new carbon skeleton from the oleoresin ofAbies sibirica

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Abstract

The structure and stereochemistry of abiesonic acid — a new triterpenoid with a modified 3,4-secolanostane carbon skeleton isolated in the form of the dimethyl ester from the oleoresin of the Siberian fir — has been established with the aid of x-ray structural analysis. On irradiation with UV light, this ester is converted reversibly into its 24Z- isomer.

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Authors
  1. V. A. Raldugin
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  2. Yu. V. Gatilov
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  3. I. Yu. Bagryanskaya
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  4. N. I. Yaroshenko
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Additional information

Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the USSR Academy of Sciences. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 585–588, September–October, 1986.

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Raldugin, V.A., Gatilov, Y.V., Bagryanskaya, I.Y. et al. Triterpenoids fromAbies species. I. Abiesonic acid — A triterpenoid with a new carbon skeleton from the oleoresin ofAbies sibirica . Chem Nat Compd 22, 548–552 (1986). https://doi.org/10.1007/BF00599258

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  • DOI: https://doi.org/10.1007/BF00599258

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