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Spectrophotometric investigation of the kinetics of the oxidation of model compounds and lignin by a peroxidase-H2O2 complex

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Abstract

It has been established that in relation to the increase in the maximum initial rate of oxidation of model compounds and of lignin by a peroxidase-H2O2 complex, the substances studied form the following sequence: guaiacol,α-guaiacylpropanol, ferulic acid,α-guaiacylpropanone, andα-lignin. On the basis of the results of the investigation it is suggested that the oxidation of lignin is carried out by a peroxidase-O2 complex. With a rise in the concentration of hydrogen peroxide the oxidation of model compounds is inhibited.

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Siberian Scientific-Research Pulp and Board Institute, Bratsk. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 109–112, January–February, 1982.

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Strel'skii, V.A., Beigel'man, A.V. & Chupka, É.I. Spectrophotometric investigation of the kinetics of the oxidation of model compounds and lignin by a peroxidase-H2O2 complex. Chem Nat Compd 18, 102–105 (1982). https://doi.org/10.1007/BF00581607

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  • DOI: https://doi.org/10.1007/BF00581607

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