Abstract
The stereoisomerism of compounds of the matrine series is considered on the basis of the authors' own x-ray structural studies of these alkaloids. A corrected series of eight stereoisomers has been drawn up. It has been shown that the numbers of theoretically possible stereoisomers of matrine is thirty-two.
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Literature cited
H. Kondo and V. Sato, J. Pharm. Soc. Jpn.,41, 1 (1921).
B. T. Ibragimov, S. A. Talipov, G. N. Tishenko, Yu. K. Kushmuradov, and T. F. Aripov, Kristallografiya,23, 1189 (1978).
F. Bohlmann, W. Weise, D. Rahtz, and Ch. Arndt, Chem. Ber.,91, 2176 (1958).
A. Ueno, K. Morinaga, S. Fukushima, Y. Iitaka, Y. Koiso, and S. Okuda, Chem. Pharm. Bull.,23, 2560 (1975).
B. T. Ibragimov, G. N. Tishenko, Yu. K. Kushmuradov, T. F. Aripov, and A. S. Sadykov, Khim. Prir. Soedin., 416 (1979).
B. T. Ibragimov, G. N. Tishenko, Yu. K. Kushmuradov, T. F. Aripov, and A. S. Sadykov, Khim. Prir. Soedin., 355 (1979).
B. T. Ibragimov, S. A. Talipov, G. N. Tishchenko, Yu. K. Kushmuradov, and T. F. Aripov, Khim. Prir. Soedin., 586 (1979).
B. T. Ibragimov, S. A. Talipov, G. N. Tishchenko, Yu. K. Kushmuradov, and T. F. Aripov, Khim. Prir. Soedin., 588 (1979).
B. T. Abragimov, S. A. Talipov, Yu. K. Kushmuradov, and T. F. Aripov, Khim. Prir. Soedin., 597 (1981).
F. G. Kamaev, V. B. Leont'ev, Kh. A. Aslamov, Yu. V. Ustynyuk, and A. S. Sadykov, Khim. Prir. Soedin., 744 (1974).
T. E. Monakhova, O. N. Tolkachev, V. E. Kabanov, M. E. Perel'son, and N. F. Proskurnina, Khim. Prir. Soedin., 472 (1974).
S. Zunnunzhanov, S. Iskandarov, and S. Yu. Yunusov, Khim. Prir. Soedin., 851 (1971).
R. S. Cahn, C. Ingold, and V. Prelog, Angew. Chem. Int. Ed.,5, 385 (1966).
I. C. Schwartz, Chem. Commun., 505 (1973).
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Institute of Bioorganic Chemistry, Academy of Sciences of the Uzbek SSR, Tashkent. Institute of Crystallography, Academy of Sciences of the USSR, Moscow. V. I. Lenin Tashkent State University. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 71–75, January–February, 1982.
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Ibragimov, B.T., Tishchenko, G.N., Kushmuradov, Y.K. et al. Stereoisomerism of the matrine alkaloids. Chem Nat Compd 18, 66–69 (1982). https://doi.org/10.1007/BF00581599
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DOI: https://doi.org/10.1007/BF00581599