Advertisement

Chemistry of Natural Compounds

, Volume 18, Issue 1, pp 44–46 | Cite as

A new terpenoid coumarin fromFerula kopetdaghensis

  • A. A. Nabiev
  • T. Kh. Khasanov
  • V. M. Malikov
Article
  • 59 Downloads

Abstract

From the roots ofFerula kopetdaghensis Eug. Kor. have been isolated nevskin and isosamarcandin and a new terpenoid coumarin kopeolone, C24H30O5, M+ 398, mp 125–126°C, [α]D18 +70° (c 0.1, ethanol). On the basis of UV, IR, PMR, and mass spectrometry, and also of transformation into farnesiferols B and C, the configurations of kopeolone, kopeolin, kopeoside, fekrol, kopetdaghin, and fekolin have been established. The configuration of farnesiferol C suggested previously has been confirmed.

Keywords

Coumarin Sulfuric Acid Solution Vinylmethyl Equatorial Orientation Oxymethylene 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    A. A. Nabiev, T. Kh. Khasanov, and V. M. Malikov, Khim. Prir. Soedin., 516 (1978).Google Scholar
  2. 2.
    A. A. Nabiev, T. Kh. Khasanov, and V. M. Malikov, Khim. Prir. Soedin., 17 (1979).Google Scholar
  3. 3.
    V. Yu. Bagirov and N. P. Kir'yalov, Khim. Prir. Soedin., 387 (1972).Google Scholar
  4. 4.
    V. Yu. Bagirov, V. I. Sheichenko, and A. I. Ban'kovskii, Khim. Prir. Soedin., 450 (1976).Google Scholar
  5. 5.
    N. P. Kir'yalov and G. V. Bukreeva, Khim. Prir. Soedin., 643 (1972).Google Scholar
  6. 6.
    V. N. Borisov, A. I. Ban'kovskii, V. I. Sheichenko, and V. S. Kabanov, Khim. Prir. Soedin., 786 (1974).Google Scholar
  7. 7.
    Kh. M. Kamilov and G. K. Nikonov, Khim. Prir. Soedin., 308 (1973).Google Scholar
  8. 8.
    L. Caglioti, H. Naef, D. Arigoni, and O. Jeger, Helv. Chim. Acta,41, 2278 (1958).CrossRefGoogle Scholar
  9. 9.
    L. Caglioti, H. Naef, D. Arigoni, and O. Teger, Helv. Chim. Acta,42, 2557 (1959).CrossRefGoogle Scholar
  10. 10.
    V. Yu. Bagirov, R. Yu. Gasanova, O. I. Burma, and A. I. Ban'kovskii, Khim. Prir. Soedin., 279 (1977).Google Scholar
  11. 11.
    D. G. Turabelidze and É. P. Kemertelidze, Khim. Prir. Soedin., 657 (1976).Google Scholar
  12. 12.
    E. E. Tamelen and R. M. Coates, Chem. Commun.,13, 413 (1966).Google Scholar
  13. 13.
    Kh. M. Kamilov and G. K. Nikonov, Khim. Prir. Soedin., 422 (1974).Google Scholar
  14. 14.
    N. V. Veselovskaya, Yu. E. Sklyar, D. A. Fesenko, and M. G. Pimenov, Khim. Prir. Soedin., 851 (1979).Google Scholar

Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • A. A. Nabiev
  • T. Kh. Khasanov
  • V. M. Malikov

There are no affiliations available

Personalised recommendations