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Heterogeneous hydrogenation of 3,7,7-trimethylcyclohepta-1,3,5-triene

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Abstract

It has been shown that the intermediate products of the hydrogenation of 3,7,7-trimethylcyclohepta-1,3,5-triene on platinum black are 2- and 3-carenes, in addition to olefins and dienes of the 1,1,4-trimethylcycloheptane series. The final hydrogenation product contains 96% of 1,1,4-trimethylcycloheptane and 4% of caranes.

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Institute of Physical Organic Chemistry, Academy of Sciences of the Belorussian SSR, Minsk. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 450–453, July–August, 1983.

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Manukov, É.N., Chuiko, V.A. Heterogeneous hydrogenation of 3,7,7-trimethylcyclohepta-1,3,5-triene. Chem Nat Compd 19, 422–425 (1983). https://doi.org/10.1007/BF00575696

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