Skip to main content
SpringerLink
Log in

Synthesis and structure of methyl-substituted 1,3-Dioxa-2-Silacylohexanes

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of dimethyl(diethylthio)silane with 1,3-diols gave methyl-substituted 1,3-dioxa-2-silacyclohexanes.1H and13C NMR spectroscopy were used to study the configuration and predominant conformations of the compounds studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. M. G. Voronkov and Yu. P. Romadan, Khim. Geterotsikl. Soedin., No. 6, 879 (1966).

    Google Scholar 

  2. R. H. Krieble and C. A. Burkhard, J. Am. Chem. Soc.,69, No. 11, 2689 (1947).

    Google Scholar 

  3. R. P. Narain and A. J. Kaur, Indian Chem. J.,A18, No. 6, 522 (1979).

    Google Scholar 

  4. F. Kober and J. Ruhlw, J. Organometall. Chem.,101, 57 (1976).

    Google Scholar 

  5. L. W. Breed, W. J. Haggerty, and J. Harvey, J. Org. Chem.,25, No. 10, 556 (1960).

    Google Scholar 

  6. M. G. Voronkov, Yu. P. Romadan, Yu. P. Pestunovich, and I. B. Mazheika, Khim. Geterotsikl. Soedin., No. 6, 972 (1968).

    Google Scholar 

  7. R. P. Narain and A. J. Kaur, Indian Chem. J.,A16, No. 4, 355 (1978).

    Google Scholar 

  8. R. P. Narain and A. J. Kaur, Indian J. Chem. Soc.,154, 504 (1977).

    Google Scholar 

  9. V. I. Larionov, L. F. Lapuka, R. S. Musavirov, S. S. Zlotskii, and D. L. Rakhmankulov, Zh. Obshch. Khim.,52, 2280 (1982).

    Google Scholar 

  10. M. G. Voronkov, V. P. Davydova, and B. N. Dolgov, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk No. 6, 698 (1958).

    Google Scholar 

  11. V. P. Davydova and M. G. Voronkov, Zh. Obshch. Khim.,28 1979 (1958).

    Google Scholar 

  12. K. A. Andrianov, T. K. Dzhashiashvili, V. V. Astakhin, and G. N. Shumakova, Izv. Akad. Nauk SSSR, Ser. Khim., No. 12, 2229 (1966).

    Google Scholar 

  13. L. Birkofer and O. Stuhl, J. Organometall. Chem.,187, 21 (1980).

    Google Scholar 

  14. L. Birkofer and O. Stuhl, J. Organometall. Chem.,164, 16 (1979).

    Google Scholar 

  15. L. Birkofer and O. Stuhl, J. Organometall. Chem.,177, 16 (1979).

    Google Scholar 

  16. R. S. Musavirov, L. F. Lapuka, E. P. Nedogrei, V. I. Larionov, I. A. Kudasheva, E. A. Kantor, S. S. Zlotskii, and D. L. Rakhmankulov, Dokl. Akad. Nauk SSSR,270, 616 (1983).

    Google Scholar 

  17. V. I. Larionov, R. S. Musaviron, E. A. Kantor, S. S. Zlotskii, D. L. Rakhmankulov, and R. A. Karakhanov, Dokl. Akad. Nauk SSSR,255, 255 (1980).

    Google Scholar 

  18. R. S. Musavirov, E. P. Nedogrei, S. S. Zlotskii, L. F. Lapuka, E. A. Kantor, and D. L. Rakhmankulov, Zh. Obshch. Khim.,52, 921 (1982).

    Google Scholar 

  19. I. I. Lapkin, T. N. Povarnitsina, and T. Yu. Denisova, Zh. Obshch. Khim.,44, 123 (1974).

    Google Scholar 

  20. I. I. Lapkin, T. N. Povarnitsina, and T. Yu. Subocheva, USSR Inventor's Certificate No. 374314; Byul. Izobr., No. 15, 51 (1973).

  21. I. I. Lapkin, T. N. Povarnitsina, and T. Yu. Denisova, Zh. Obshch. Khim.,42, 2032 (1972).

    Google Scholar 

  22. I. I. Lapkin, T. N. Povarnitsina, and V. V. Dvinskikh, Zh. Obshch. Khim.,48, 607 (1978).

    Google Scholar 

  23. I. I. Lapkin, T. N. Povarnitsina, and T. Yu. Subocheva, Zh. Obshch. Khim.,42, 399 (1972).

    Google Scholar 

  24. C. Couret, J. Satge, and F. Couret, J. Organometall. Chem.,57, 287 (1973).

    Google Scholar 

  25. S. N. Borisov, M. G. Voronkov, and É. Ya. Lukevits, Organosilicon Derivatives of Phosphorus and Sulfur [in Russian], Izd. Khimiya, Leningrad (1968), p. 292.

    Google Scholar 

  26. M. G. Voronkov, V. A. Petunovich, and Yu. P. Romadan, Khim. Geterotsikl. Soedin., No. 1, 178 (1968).

    Google Scholar 

  27. D. G. Hellier, Chem. Ind., No. 41, 1323 (1970).

    Google Scholar 

  28. P. Albriktsen and S. Heggelund, Acta Chem. Scand.,28B, No. 5, 573 (1974).

    Google Scholar 

  29. L. K. Yudlasheva, R. P. Arshinova, Yu. Yu. Samitov, Yu. P. Romadan, and M. G. Voronkov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 2, 323 (1974).

    Google Scholar 

  30. F. Cotton and G. Wilkinson, Fundamentals of Inorganic Chemistry [Russian translation], Izd. Mir, Moscow (1979), p. 220.

    Google Scholar 

  31. A. F. Skryshevskii, V. P. Klochkov, and Yu. V. Pasechnik, Zh. Strukt. Khim.,2, 140 (1961).

    Google Scholar 

  32. M. Anteunis, D. Tavernier, and F. Borremans, Heterocycles,4 293 (1976).

    Google Scholar 

  33. C. H. Bushweller, J. W. O'Nell, and H. S. Bilofsky, Tetrahedron,27, 3065 (1971).

    Google Scholar 

  34. H. Booth, Tetrahedron Lett., No. 23, 1449 (1964).

    Google Scholar 

  35. J. Delmau and C. Barbier, J. Chem. Phys.,41, No. 4, 1106 (1964).

    Google Scholar 

  36. K. Pihlaja and R. Auras, Acta Chem. Scand.,26, No. 3, 252 (1972).

    Google Scholar 

  37. K. Pihlaja and R. Auras, Acta Chem. Scand.,24, 531 (1970).

    Google Scholar 

  38. Yu. Yu. Samitov, Khim. Geterotsikl. Soedin., No. 12, 1587 (1978).

    Google Scholar 

  39. Yu. Yu. Samitov, Dokl. Akad. Nauk SSSR,164, 347 (1965).

    Google Scholar 

  40. A. V. Bogatskii, Yu. Yu. Samitov, S. P. Egorova, T. A. Zakharchenko, Zh. Org. Khim.,5, 830 (1969).

    Google Scholar 

  41. J. Delmau and J. Duplan, Tetrahedron Lett., No. 6, 559 (1966); No. 24, 2693 (1966).

    Google Scholar 

  42. V. M. Gittins, E. Wynn-Jones, and R. F. White, in: Internal Molecular Rotation [Russian translation], Izd. Mir, Moscow (1977), p. 352.

    Google Scholar 

  43. N. Spassky, Comp. Rend. Chim. Org., No. 2, 2371 (1960).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ufa Petroleum Institute, 450062, Ufa

    R. S. Musavirov, E. P. Nedogrei, L. F. Lapuka, E. A. Kantor, R. S. Sarmanaev & D. L. Rakhmankulov

Authors
  1. R. S. Musavirov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. P. Nedogrei
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. F. Lapuka
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. A. Kantor
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. S. Sarmanaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. D. L. Rakhmankulov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 845–851, June, 1986.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Musavirov, R.S., Nedogrei, E.P., Lapuka, L.F. et al. Synthesis and structure of methyl-substituted 1,3-Dioxa-2-Silacylohexanes. Chem Heterocycl Compd 22, 670–675 (1986). https://doi.org/10.1007/BF00575253

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00575253

Keywords

Search

Navigation