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Chemistry of Heterocyclic Compounds

, Volume 22, Issue 6, pp 654–663 | Cite as

Synthesis, structure, and spectral properties of some bioxazoles

  • L. I. Belen'kii
  • M. A. Cheskis
  • V. P. Zvolinskii
  • A. E. Obukhov
Article

Abstract

Syntheses of systems containing two oxazole rings [2′-phenyl-, 2′-(2-furyl)-, and 2′-(2-thienyl)-2,5′-bioxazoles, and 2,2′-(2,5-furylene)bisoxazole] from aldehydes obtained by formylating 2-phenyl-, 2-(2-furyl)-, and 2-(2-thienyl)oxazole have been developed. Terephthalate and thiophen-2,5-dicarboxylate esters have been used to obtain 2,2′-(1,4-phenylene)- and 2,2′-(2,5-thienylene)bisoxazoles. The PMR, UV, and luminescence spectra of these systems have been examined, and quantum chemical calculations carried out in the PPP approximation.

Keywords

Ester Organic Chemistry Aldehyde Phenyl Quantum Chemical 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • L. I. Belen'kii
    • 1
    • 2
  • M. A. Cheskis
    • 1
    • 2
  • V. P. Zvolinskii
    • 1
    • 2
  • A. E. Obukhov
    • 1
    • 2
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of USSRMoscow
  2. 2.P. Lumumba People's Friendship UniversityMoscow

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