Abstract
Condensation of pyrrole with benzaldehydes in a mixture of xylene and chloroacetic acid gives a series of substituted tetraphenylporphins with yields exceeding the yields of porphyrins synthesized according to known preparative methods.
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B. D. Berezin, Coordination Compounds of Porphyrins and Phthalocyanine [in Russian], Nauka, Moscow (1978), p. 280.
A. Treibs and N. Haberle, Liebigs Ann. Chem.,718, 183 (1968).
A. D. Adler, F. R. Longo, J. D. Finarelli, J. Goldmacher, J. Assour, and B. Korsakoff, J. Org. Chem.,32, 476 (1967).
N. Datta-Gupta and F. Bardos, J. Heterocycl. Chem.,3, 495 (1966).
F. R. Longo, M. G. Finarelli, and J. B. Kim. J. Heterocycl. Chem.,6, 927 (1969).
A, D. Adler, L. Sklar, and F. R. Longo, J. Heterocycl. Chem.,5, 669 (1968).
A. S. Semeikin, O. I. Koifman, and B. D. Berezin, USSR, Inventor 's. Certificate No. 1,118,642; Byull. Izobret., No. 38, 68 (1984).
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 798–801, June, 1983.
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Semeikin, A.S., Koifman, O.I. & Berezin, B.D. Improved method for synthesis of substituted tetraphenylporphins. Chem Heterocycl Compd 22, 629–632 (1986). https://doi.org/10.1007/BF00575244
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DOI: https://doi.org/10.1007/BF00575244