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Chemistry of Heterocyclic Compounds

, Volume 22, Issue 6, pp 620–624 | Cite as

Catalytic properties of rhodium hydridocarbonyl trithienyl-phosphine complexes in the homogeneous hydrogenation and isomerization of unsaturated compounds

  • A. A. Dudinov
  • Ya. L. Gol'dfarb
  • E. F. Litvin
  • L. M. Kozlova
  • B. S. Bogdanov
Article

Abstract

Syntheses are reported for trithienylphosphine analogs of hydridocarbonyltris (triphenylphosphine) rhodium(I) and the catalytic activity of these analogs in the hydrogenation and isomerization of terminal olefins was demonstrated. The PMR chemical shifts and form of the signals of the hydride hydrogen atom of these rhodium hydridocarbonyl complexes correlate with their catalytic properties in homogeneous hydrogenation and isomerization.

Keywords

Hydrogenation Organic Chemistry Catalytic Activity Chemical Shift Hydrogen Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • A. A. Dudinov
    • 1
  • Ya. L. Gol'dfarb
    • 1
  • E. F. Litvin
    • 1
  • L. M. Kozlova
    • 1
  • B. S. Bogdanov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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